THE ANALYSIS OF GAS CONSUMPTION IN THE REACTION OF FE AND CU IN216O/H218O/O2 GAS-MIXTURES

被引：32

作者：

HULTQUIST, G ^{[1
]}

GRASJO, L ^{[1
]}

LU, Q ^{[1
]}

AKERMARK, T ^{[1
]}

机构：

[1] ROYAL INST TECHNOL,DEPT CHEM,DIV PHYS CHEM,S-10044 STOCKHOLM 70,SWEDEN

来源：

CORROSION SCIENCE | 1994年 / 36卷 / 09期

基金：

瑞典研究理事会;

关键词：

D O I：

10.1016/0010-938X(94)90045-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Some general considerations in the analysis of consumption and release of gas components in reactions of a metal in H-2/H2O/O2 gas are presented. Reactions of iron and copper at 160-300-degrees-C in H-2-O-16/H-2-O-18/O2 gas in the mbar pressure range were studied with mass spectrometry in a virtually closed reaction chamber. Data on oxygen and hydrogen uptake in the reaction products and fraction of oxygen coming from reaction with water lead to conclusions concerning partial and complete water dissociation in the reactions with the metals.

引用

页码：1459 / 1471

页数：13

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