CHEMISTRY AND STRUCTURE OF ANTI-(Z)-BIS(FENCHYLIDENE) AND SYN-(E)-BIS(FENCHYLIDENE)

被引：13

作者：

BROOKS, PR

BISHOP, R

COUNTER, JA

TIEKINK, ERT

机构：

[1] UNIV NEW S WALES,SCH CHEM,KENSINGTON,NSW 2033,AUSTRALIA

[2] UNIV ADELAIDE,DEPT CHEM,ADELAIDE,SA 5000,AUSTRALIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 06期

关键词：

D O I：

10.1021/jo00085a027

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

anti-(Z)-Bis(fenchylidene) (3) has been prepared. The crystal structure of 3 displays an alkene torsion angle of 17.0-degrees and deformations of the carbon-carbon bond lengths and angles around the alkene center. The chemical behavior of syn-(E)-bis(fenchylidene) (2) and 3 was found to be affected by the steric strain.

引用

页码：1365 / 1368

页数：4

共 33 条

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