FREE ACID PORPHYRIN AND ITS CONJUGATED MONOANION

被引：31

作者：

BRAUN, J

HASENFRATZ, C

SCHWESINGER, R

LIMBACH, HH

机构：

[1] FREE UNIV BERLIN,INST ORGAN CHEM,D-14195 BERLIN,GERMANY

[2] UNIV FREIBURG,INST ORGAN CHEM,FREIBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 21期

关键词：

D O I：

10.1002/anie.199422151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An absolute pKa value of about 36 in acetonitrile is obtained for porphyrin from its reaction with phosphazene bases. The monoanion 1 is stable in aprotic solvents and was characterized by NMR and UV/ Vis spectroscopy. The remaining central proton in the monoanion migrates between the four nitrogen atoms much faster than the two protons in the parent compound. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2215 / 2217

页数：3

共 69 条

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