DIPHOSPHATOALUMINATE A NEW COMPLEX ANION AND HYDRATES OF ITS TETRAMETHYLAMMONIUM SALT

被引:6
作者
KUHL, G
机构
[1] Central Research Division Laboratory, Mobil Research and Development Corporation, Princeton, NJ 08540
来源
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 04期
关键词
D O I
10.1016/0022-1902(69)80152-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The existence of a diphosphatoaluminate anion in aqueous solution has been established. Its tetramethylammonium salt has been isolated as the 10-hydrate. By carrying out dehydration experiments, evidence was found for the existence of the 4-, 2-, and 1·5 hydrates. The 4- and 1·5-hydrates have been prepared, whereas the 2-hydrate is unstable and dehydrates easily to the 1·5-hydrate. © 1969.
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页码:1043 / &
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