INTERFERENCE TRANSITION ELECTRIC-DIPOLE MECHANISM IN MCD SPECTROSCOPY

被引：2

作者：

DUBICKI, L

FERGUSON, J

机构：

[1] Research School of Chemistry, Australian National University, Canberra

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)87248-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Previously unexplained MCD of MnNi pairs, in cubic KZnF3, is shown to arise from the interference between single-ion and exchange-induced (pair) transition electric dipole moments. In general, MCD may detect similar interference for spin-forbidden charge-transfer transitions in mononuclear metal-ion complexes as well as spin-forbidden ligand-field transitions in polynuclear complexes. © 1979.

引用

页码：507 / 510

页数：4

共 9 条

[1] EXCHANGE INTERACTIONS IN A TRIGONAL CHROMIUM-(III) PAIR .1. THEORY
DUBICKI, L
TANABE, Y
[J]. MOLECULAR PHYSICS, 1977, 34 (06) : 1531 - 1543
[2] DUBICKI L, UNPUBLISHED
[3] HIGH-RESOLUTION PHOSPHORESCENCE EXCITATION SPECTROSCOPY OF EXCHANGE COUPLED MN2+ PAIRS IN KMGF3 AND KZNF3
FERGUSON, J
GUDEL, HU
KRAUSZ, ER
GUGGENHEIM, HJ
[J]. MOLECULAR PHYSICS, 1974, 28 (04) : 893 - 904
[4] EXCHANGE EFFECTS IN ELECTRONIC ABSORPTION SPECTRUM OF MN(2) IN PEROVSKITE FLUORIDES
FERGUSON, J
GUGGENHEIM, HJ
TANABE, Y
[J]. JOURNAL OF APPLIED PHYSICS, 1965, 36 (3P2) : 1046 - +
[5] HIGH-RESOLUTION MCD SPECTROSCOPY OF TRANSITION-METAL IONS IN FLUORIDE-CRYSTALS .1. A-6(1G)-]A-4(1G), E-4(GA)(G-4) NO-PHONON TRANSITIONS OF MN2+ IN KMGF3 AND KZNF3
FERGUSON, J
KRAUSZ, ER
GUGGENHEIM, HJ
[J]. MOLECULAR PHYSICS, 1974, 27 (03) : 577 - 591
[6] ABSORPTION OF LIGHT BY PAIRS OF EXCHANGE-COUPLED MANGANESE AND NICKEL IONS IN CUBIC PEROVSKITE FLUORIDES
FERGUSON, J
GUGGENHE.HJ
TANABE, Y
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (04) : 1134 - &
[7] 4EG(G) EXCITON OF RBMNF3
FUJIWARA, T
TANABE, Y
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1974, 37 (06) : 1512 - 1520
[8] GUDEL HU, UNPUBLISHED
[9] MAGNON-INDUCED ELECTRIC DIPOLE TRANSITION MOMENT
TANABE, Y
MORIYA, T
SUGANO, S
[J]. PHYSICAL REVIEW LETTERS, 1965, 15 (26) : 1023 - &

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