STRUCTURE OF ACETONITRILE(DICHLORO)(PHENYL)BIS(TRIPHENYLSTIBINE)RHODIUM(III)

被引：14

作者：

CINI, R

GIORGI, G

PERICCIOLI, E

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190010320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Rh(C44H38Cl2NSb2)], M(r) = 998.1, monoclinic, C2/c, a = 13.816 (2), b = 13.472 (2), c = 22.075 (3) angstrom, beta = 95.61 (2)-degrees, V = 4089 angstrom 3, Z = 4, D(x) = 1.62 Mg m-3, lambda(Mo K-alpha) = 0.7107 angstrom, mu = 18.75 cm-1, F(000) = 1960, T = 295 K, R = 0.051 for 2718 unique observed reflections. The structure consists of neutral complex molecules with an octahedral coordination sphere containing two chlorine ligands, two antimony atoms from triphenylstibine (SbPh3), a nitrogen atom from acetonitrile (MeCN) and a carbon atom from phenyl (Ph). The two chlorine ligands are trans to each other and the Rh-Cl bond distances are 2.360 (2) angstrom. The Rh-N bond length of 2.163 (9) angstrom is somewhat large, indicating a significant trans influence of the Ph ligand. The Rh-Sb distance is 2.588 (1) angstrom.

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页码：716 / 719

页数：4

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共 21 条

[1] NOVEL DIASTEREOMERS WITH OPPOSITE CHIRALITY AT RUTHENIUM FORMED BY N7, ALPHA-PO4 CHELATION OF 5'-DGMP TO THE ANTIMETASTATIC AGENT TRANS-RUCL2(DMSO)4 - NMR AND CD EVIDENCE [J].

ALESSIO, E ;

XU, YH ;

CAUCI, S ;

MESTRONI, G ;

QUADRIFOGLIO, F ;

VIGLINO, P ;

MARZILLI, LG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) :7068-7071

[2] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[3] STEREOSPECIFIC INTERACTIONS BETWEEN TETRAKIS(MU-CARBOXYLATO)DIRHODIUM(II) ANTITUMOR AGENTS AND NUCLEIC-ACID BASES - CRYSTAL-STRUCTURE OF [RH2(ACETATO)4(AAMP)].3.5H2O (AAMP = 4-AMINO-5-(AMINOMETHYL)-2-METHYLPYRIMIDINE) [J].

AOKI, K ;

YAMAZAKI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (12) :3691-3692

[4] INTERLIGAND INTERACTIONS AFFECTING SPECIFIC METAL-BONDING TO NUCLEIC-ACID BASES - X-RAY CRYSTAL-STRUCTURE OF TETRAKIS-MU-ACETAMIDATOBIS(THEOPHYLLINE)RHODIUM(II)-RHODIUM(III) NITRATE MONOHYDRATE [J].

AOKI, K ;

HOSHINO, M ;

OKADA, T ;

YAMAZAKI, H ;

SEKIZAWA, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (04) :314-316

[5] GROWTH OF MICROORGANISMS IN PRESENCE OF TRANSITION METAL COMPLEXES - ANTIBACTERIAL ACTIVITY OF TRANS-DIHALOGENOTETRAPYRIDINERHODIUM(3) SALTS [J].

BROMFIELD, RJ ;

DAINTY, RH ;

GILLARD, RD ;

HEATON, BT .

NATURE, 1969, 223 (5207) :735-+

[6] RUTHENIUM(II)-6-MERCAPTOPURINE COMPLEX SYNTHESIS AND SOLUTION PROPERTIES - MOLECULAR AND CRYSTAL-STRUCTURE OF BIS(6-MERCAPTOPURINE)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE [J].

CINI, R ;

CINQUANTINI, A ;

SABAT, M ;

MARZILLI, LG .

INORGANIC CHEMISTRY, 1985, 24 (23) :3903-3908

[7] CRYSTAL AND MOLECULAR-STRUCTURE OF TRICHLORO(DIMETHYL "SULPHOXIDE)BIS-PYRIDINERHODIUM(III) [J].

COLAMARINO, P ;

ORIOLI, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (10) :845-848

[8] ANTITUMOR ACTION OF PLANAR, ORGANOMETALLIC RHODIUM (I) COMPLEXES [J].

GIRALDI, T ;

ZASSINOVICH, G ;

MESTRONI, G .

CHEMICO-BIOLOGICAL INTERACTIONS, 1974, 9 (06) :389-394

[9] PARTIAL NUCLEOPHILIC DISPLACEMENT OF CHLORIDE IN MER-TRICHLOROTRIS(TRIPHENYLSTIBINE)RHODIUM(III) [J].

HILL, WE ;

MCAULIFF.CA .

INORGANIC CHEMISTRY, 1974, 13 (06) :1524-1525

[10]

JOHNSON CK, 1971, ORNL3794 REP