THE EFFECTS OF FLUID DENSITY ON THE ROTATIONAL RAMAN-SPECTRUM OF HYDROGEN DISSOLVED IN SUPERCRITICAL CARBON-DIOXIDE

被引：50

作者：

HOWDLE, SM ^{[1
]}

BAGRATASHVILI, VN ^{[1
]}

机构：

[1] LASER TECHNOL CTR, TROITSK 142092, RUSSIA

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 214卷 / 02期

关键词：

D O I：

10.1016/0009-2614(93)90084-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rotational Raman spectrum of hydrogen dissolved in supercritical carbon dioxide (scCO2) is investigated. As the pressure, and hence density of the solution is increased, the lines broaden dramatically. The line broadening is compared with that of the vibrational line Q1(1) and possible explanations for the behaviour, related to solvent-solute interactions, are discussed.

引用

页码：215 / 219

页数：5

共 21 条

[1] SOLVENT-INDUCED SHIFT OF THE RAMAN-SPECTRA IN SUPERCRITICAL FLUIDS [J].