THE REACTION OF WADSWORTH-EMMONS-HORNER REAGENTS WITH O-QUINONEIMINES AND P-QUINONEIMINES

被引：20

作者：

BOULOS, LS

ARSANIOUS, MHN

机构：

[1] National Research Centre, Dokki, Cairo

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 89卷 / 1-4期

关键词：

WITTIG-HORNER REAGENTS; N,N'-3,5-CYCLOHEXADIENE-1,2-DIYLIDENEBIS (BENZAMIDE); AND N,N'-2,5-CYCLOHEXADIENE-1,4-DIYLIDENEBIS (BENZAMIDE);

D O I：

10.1080/10426509408020448

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Wittig-Horner reagents (1a-c) react with o-quinone diimine (2a) to give the respective phosphonate adducts (3a-c) and the alkylated product 4. The reaction of p-quinone diimine (2b) with the same reagents yield adducts 5, 6 and 7, respectively. Structural reasoning for the new compounds was based on compatible analytical and spectral data. The mechanism that accounts for formation of adducts 3 is illustrated in Scheme 2.

引用

页码：185 / 191

页数：7

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