RING-OPENING REACTIONS OF STRAINED-RING THIOETHERS IN METAL CLUSTER COMPLEXES - PHOTOINDUCED TRANSFORMATION OF THIETANE TO 2-PROPENETHIOLATE IN A TRIOSMIUM CLUSTER COMPLEX

被引：35

作者：

ADAMS, RD

POMPEO, MP

机构：

[1] Department of Chemistry, University of South Carolina, Columbia

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1021/om00156a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Os3(CO)11[S(CH2)3] undergoes photoassisted ring opening, CH activation, and decarbonylation to yield Os3(CO)10[m-SCH2C(H)==CH2](m-H) (2). 2 engages in a phosphine-assisted insertion reaction between the allyl group and the hydride ligand to yield Os3(CO)10-(PMe2Ph)[m-S(CH2)3] (3), which contains a novel thia-metallacyciic ring. 3 is decarbonylated at 97°C to yield the PMe2Ph derivative of 2. © 1990, American Chemical Society. All rights reserved.

引用

页码：1718 / 1720

页数：3

共 19 条

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