VOLUME CHANGES ON MIXING SOLUTIONS OF LITHIUM CHLORIDE SODIUM CHLORIDE LITHIUM SULFATE AND SODIUM SULFATE AT CONSTANT IONIC STRENGTH

被引：21

作者：

WIRTH, HE

MILLS, WL

机构：

[1] Department of Chemistry, Syracuse University, Syracuse

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1968年 / 13卷 / 01期

关键词：

D O I：

10.1021/je60036a030

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The volume changes at 25° C. on mixing two solutions of equal ionic strength were determined for the six combinations of the four electrolytes, LiCI, NaCI, Li2SO4, and Na2SO4 at ionic strengths of 1 and 4. Single-mixing experiments were made at an ionic strength of 2.25 for the six combinations, and at ionic strengths of 0.25, 0.50, 1.5, and 3.0 for the Na2SO4-NaCI system in order to determine the concentration dependence of the volume changes. The volume changes on mixing the heterionic solutions (Na2SO4-LiCI and Li2SO4-NaCI) could be calculated from the volume changes observed in homoionic solutions to within 0.03 ml. per equivalent. © 1968, American Chemical Society. All rights reserved.

引用

页码：102 / &

共 15 条

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