PREPARATION AND PROPERTIES OF TETRACYANOMETHANE

被引：23

作者：

MAYER, E

机构：

[1] Institut für Anorganische und Analytische Chemie der Universität Innsbruck, Innsbruck

来源：

MONATSHEFTE FUR CHEMIE | 1969年 / 100卷 / 02期

关键词：

D O I：

10.1007/BF00904089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of silver tricyanomethanide with cyanogen chloride yields the hitherto unreported tetracyanomethane and AgCl. Tetracyanomethane is a crystalline solid, sublimes at 60° in vacuo, decomposes above 160° and is soluble in polar solvents. The IR spectrum is discussed and an assignment of the fundamental frequencies based on Td symmetry is made. Hydrolysis with acid or alkali and the reaction with LiCl are described. © 1969 Springer-Verlag.

引用

页码：462 / &

共 10 条

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