TITANIUM-ZIRCONIUM TRIIODIDES TIXZR(1-X)I3

被引:2
作者
BHATTI, MA
COPLEY, DB
SHELTON, RAJ
机构
[1] Department of Metallurgy, University of Manchester, Manchester
来源
JOURNAL OF THE LESS-COMMON METALS | 1969年 / 18卷 / 02期
关键词
D O I
10.1016/0022-5088(69)90127-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of members of the iso-structural series TixZr(1-x)I3 (D33h-P63(mcm)), from the metals and their tetraiodides is described. Their crystal lattice parameters are found to lie on a smooth curve drawn between the end members TiI3 and ZrI3. The difficulty of retaining zirconium in the titanium-rich compound, and the resulting non-stoichiometry, is discussed in terms of the partial disproportionation of the compound. © 1969.
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页码:99 / &
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