BETA-LITHIO KETONE ENOLATES - GENERATION AND REACTIONS WITH ELECTROPHILES

被引：25

作者：

NAKAHIRA, H

RYU, I

IKEBE, M

KAMBE, N

SONODA, N

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Osaka, 565, Suita

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 02期

关键词：

D O I：

10.1002/anie.199101771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deprotonation and Sn/Li exchange transforms the ketone 1 into the title compound 2, which proves to be a most useful synthesis step. The alpha,beta-dianions of ketones react with electrophiles, whereby two different electrophiles can react sequentially.

引用

页码：177 / 179

页数：3

共 26 条

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