SPIN-LABEL STUDY OF IMMISCIBLE POLYMERS .1. INTERFACIAL-TENSION BETWEEN POLYSTYRENE AND POLYISOPRENE

被引:5
作者
CAMERON, GG
ROSS, E
MILES, IS
RICHARDSON, J
BYE, D
机构
[1] ICI PLC,WILTON MAT CTR,MIDDLESBROUGH TS6 8JE,ENGLAND
[2] ICI PLC,CORP COLLOID SCI GRP,RUNCORN WA7 4QE,ENGLAND
关键词
D O I
10.1016/0014-3057(91)90006-A
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Interfacial tensions (IT) between polyisoprene and polystyrene (PS) were measured by the sessile drop method at 433K. For a normal PS and a PS carrying a nitroxide end-group, the values of IT were 2.54 +/- 0.5 and 2.38 +/- 0.5 dyne cm-1 respectively. The close match of these values suggests that the nitroxide end-label has no strong affinity for the polyisoprene domain.
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页码:773 / 774
页数:2
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