CYCLOPENTADIENYLURANIUM(IV) COMPLEXES WITH A CHIRAL METALLIC CENTER .1. CHARACTERIZATION OF A PROCHIRAL STRUCTURE BY PMR SPECTROSCOPY

被引：4

作者：

DORMOND, A

DUVAL, C

机构：

[1] Laboratoire de Synthèse, d'Electrosynthèse Organométallique associé au CNRS (LA 33), Université de Dijon, 21004 Dijon Cédex

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 178卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94233-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of compounds (C5H4R)3UCl (R alkyl) and the two tricyclopentadienyl compounds (C5H5)2(C5H4R)UCl and C5H5(C5H4R)2UCl, (R CH(CH3)2) have been isolated and characterized by PMR spectroscopy. For the last compound, the PMR data indicate a magnetic non-equivalence for the cyclopentadienyl protons and for the methyl groups of R; both are due to the prochirality of the uranium atom. © 1979.

引用

页码：C5 / C7

页数：3

共 7 条

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