GENERATION AND GAS-PHASE REACTIVITY OF COGA+

被引：10

作者：

KRONSEDER, C

SCHINDLER, T

BERG, C

FISCHER, R

NIEDNERSCHATTEBURG, G

BONDYBEY, VE

机构：

[1] TECH UNIV MUNICH, INST PHYS & THEORET CHEM, LICHTENBERGSTR 4, D-85747 GARCHING, GERMANY

[2] TECH UNIV MUNICH, INST ANORGAN CHEM, D-85747 GARCHING, GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 475卷 / 1-2期

关键词：

COBALT; GALLIUM; MASS SPECTROMETRY; MATERIALS;

D O I：

10.1016/0022-328X(94)84029-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electron impact ionization and subsequent fragmentation of volatile but stable organometallic precursor compounds is used to release naked CoGa+ ions to transfer into and analyse by a high resolution Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometer. Gas-phase bimolecular reactions of CoGa+ ions with methanol, among others, yield two distinct isomers of (GaCH3OH)+ with significant internal excitation. Ab initio calculations using a density functional approach for CoGa+ and (GaCH3OH)+ complement the experimental findings.

引用

页码：247 / 256

页数：10

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