CYCLIC ACYLIMINES AND CYCLIC CARBINOLAMIDES .I. 2-AZAPHENALONES

被引：19

作者：

WARSHAWSKY, A

BENISHAI, D

机构：

[1] Department of Chemistry, Technion - Israel Institute of Technology, Haifa

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1969年 / 6卷 / 05期

关键词：

D O I：

10.1002/jhet.5570060515

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2‐Azaphenalone hydrochloride (VI), 2‐methyl‐1‐azaphenalonium chloride (XIV), 3‐phenyl‐2‐azaphenalone (XVIII) and 3‐phenyl‐2‐methyl‐2‐azaphenalonium chloride (XXI) were synthesized and their chemical and physical properties were studied. At room temperature they add weak nucleophiles (e.g., alcohols, amides) as well as compounds possessing active methylene groups. The methanol addition products (e.g., V) reacted thermally or in the presence of an acid catalyst with nucleophiles to give products identical with those obtained from the azaphenalone hydrochlorides. Copyright © 1969 Journal of Heterocyclic Chemistry

引用

页码：681 / +

页数：1

共 11 条

[1]

ARSENIJEVIC L, 1968, B SOC CHIM FR, P3403

[2] N-ACYL DERIVATIVES OF AROMATIC KETIMINES [J].

BANFIELD, JE ;

BROWN, GM ;

DAVEY, FH ;

DAVIES, W ;

RAMSAY, TH .

AUSTRALIAN JOURNAL OF SCIENTIFIC RESEARCH SERIES A-PHYSICAL SCIENCES, 1948, 1 (03) :330-342

[3] SYNTHESIS OF SOME HETEROCYCLIC COMPOUNDS FROM ALPHA-BENZOYLIMINOBENZYL CYANIDE AND RELATED COMPOUNDS [J].

FUJIMORI, M ;

HARUKI, E ;

IMOTO, E .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1968, 41 (06) :1372-+

[4]

HENGSUEN Y, 1965, B SOC CHIM FR, P1454

[5]

NEWMAN MS, 1941, J AM CHEM SOC, V63, P1537

[6]

WARSHAWSKY A, 1968, TETRAHEDRON LETT, P541

[7] N-ACYL-TRIHALOGENACETALDIMINE ALS REAKTIVE ZWISCHENSTUFEN BEI ELIMINIERUNGS-ADDITIONS-REAKTIONEN .3. DARSTELLUNG UND REAKTIONEN DER 1.2.2.2-TETRAHALOGEN-N-ACYL-ATHYLAMINE [J].

WEYGAND, F ;

STEGLICH, W ;

LENGYEL, I ;

FRAUNBER.F ;

MAIERHOF.A ;

OETTMEIE.W .

CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (06) :1944-&

[8]

ZAUGG HE, 1965, ORG REACTIONS, V14, P56

[9]

ZEIFMAN YV, 1965, IAN SSSR KH, P2046

[10]

ZINK J, 1901, MONATSH CHEM, V22, P988

← 1 2 →