UNUSUAL CATIONIC SINGLE-BRIDGED BINUCLEAR COMPLEXES OF GOLD(I) AND GOLD(III)

被引：62

作者：

USON, R

LAGUNA, A

CASTRILLO, MV

机构：

[1] Department of Inorganic Chemistry, University of Zaragoza

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1979年 / 9卷 / 04期

关键词：

D O I：

10.1080/00945717908069748

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of AuXPPh3 (X being a potentially bridging ligand) with Au(OClO3)PPh3 (1:1) or with AgBF4 lead to cationic single-bridged binuclear gold(I) complexes of the [Ph3PAu-X-AuPPh3]A type (A = ClO4 or BF4). The corresponding gold(III) complexes of the (Ph3P(C6F5)2Au-X-Au(C6F5)2PPh3]A type are obtained by similar reactions of Au(A) (C6F5)2PPh3 with AuX (C6F5)2PPh3. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：317 / 324

页数：8

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