CRACKING REACTIONS OF C6 PARAFFINS ON HZSM-5

被引：42

作者：

ABBOT, J

机构：

[1] Chemistry Department, University of Tasmania, TAS

来源：

APPLIED CATALYSIS | 1990年 / 57卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0166-9834(00)80727-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cracking reactions on HZSM-5 at 500°C have been studied for n-hexane, 2-methylpentane, 3-methylpentane and 2,3-dimethylbutane. A detailed examination of selectivity and kinetic phenomena is consistent with a cracking mechanism initiated via protonation of the paraffins at Brønsted sites. The study also reveals that previous conclusions based on the "α-test" and "constraint index" may need to be re-examined. © 1990.

引用

页码：105 / 125

页数：21

共 37 条

[1] CATALYTIC REACTIONS OF N-DODECANE ON ALUMINOSILICATES
ABBOT, J
WOJCIECHOWSKI, BW
[J]. JOURNAL OF CATALYSIS, 1989, 115 (02) : 521 - 531
[2] CATALYTIC CRACKING ON HY AND HZSM-5 OF A FISCHER-TROPSCH PRODUCT
ABBOT, J
WOJCIECHOWSKI, BW
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1985, 24 (04): : 501 - 507
[3] THE MECHANISM OF CATALYTIC CRACKING OF NORMAL-ALKENES ON ZSM-5 ZEOLITE
ABBOT, J
WOJCIECHOWSKI, BW
[J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1985, 63 (03) : 462 - 469
[4] HYDROGEN TRANSFER-REACTIONS IN THE CATALYTIC CRACKING OF PARAFFINS
ABBOT, J
WOJCIECHOWSKI, BW
[J]. JOURNAL OF CATALYSIS, 1987, 107 (02) : 451 - 462
[5] THE EFFECT OF TEMPERATURE ON THE PRODUCT DISTRIBUTION AND KINETICS OF REACTIONS OF NORMAL-HEXADECANE ON HY ZEOLITE
ABBOT, J
WOJCIECHOWSKI, BW
[J]. JOURNAL OF CATALYSIS, 1988, 109 (02) : 274 - 283
[6] CATALYTIC REACTIONS OF BRANCHED PARAFFINS ON HY ZEOLITE
ABBOT, J
WOJCIECHOWSKI, BW
[J]. JOURNAL OF CATALYSIS, 1988, 113 (02) : 353 - 366
[7] CATALYTIC REACTIONS OF NORMAL-HEXANE ON HY ZEOLITE
ABBOT, J
WOJCIECHOWSKI, BW
[J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1988, 66 (05) : 825 - 830
[8] KINETICS OF REACTIONS OF C-8 OLEFINS ON HY ZEOLITE
ABBOT, J
WOJCIECHOWSKI, BW
[J]. JOURNAL OF CATALYSIS, 1987, 108 (02) : 346 - 355
[9] KINETICS OF CATALYTIC CRACKING OF N-PARAFFINS ON HY ZEOLITE
ABBOT, J
WOJCIECHOWSKI, BW
[J]. JOURNAL OF CATALYSIS, 1987, 104 (01) : 80 - 85
[10] ROLE OF BRONSTED AND LEWIS ACID SITES DURING CRACKING REACTIONS OF ALKANES
ABBOT, J
[J]. APPLIED CATALYSIS, 1989, 47 (01): : 33 - 44

← 1 2 3 4 →