NEW DICARBENESTANNYLENE COMPLEXES AND NITROGEN-TIN YLIDE COMPLEXES BY USE OF (SN(NME2)2)2 AS COMPLEX LIGAND

被引：19

作者：

PETZ, W

机构：

[1] Fachbereich Chemie der Universität Marburg/Lahn, Lahnberge

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94321-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Sn(NMe2)2]2 with photochemically generated M(CO)5 · THF complexes yields the dimeric nitrogen-tin ylide complexes [(CO)5MSn(NMe2)2]2 (M = Cr, Mo, W). With pentacarbonyliron by addition of the two SnN bonds to neighbouring carbonyl groups dicarbene-stannylene complexes are formed. The structures of these compounds are deduced from IR and 1H NMR spectra. © 1979.

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页码：199 / 207

页数：9

相关论文

共 18 条

[1] TRIMETHYLGALLIUM .6. INFRARED SPECTRA AND PHASE TRANSITIONS OF DIMETHYLAMINO-DERIVATIVES OF DIMETHYL-ALUMINIUM -GALLIUM AND -INDIUM [J].

BEACHLEY, OT ;

COATES, GE ;

KOHNSTAM, G .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (MAY) :3248-&

[2] DERIVATIVES OF DIVALENT GERMANIUM, TIN AND LEAD .15. SOME REACTIONS OF DICYCLOPENTADIENYLTIN AND BIS(METHYLCYCLOPENTADIENYL)TIN WITH METAL-CARBONYL COMPOUNDS [J].

CORNWELL, AB ;

HARRISON, PG ;

RICHARDS, JA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 108 (01) :47-60

[3] COORDINATION CHEMISTRY OF HEAVY-ATOM GROUP-IV DONORS, AND CRYSTAL AND MOLECULAR-STRUCTURE OF [(ME3SI)2CH]2SNCR(CO)5 [J].

COTTON, JD ;

DAVISON, PJ ;

GOLDBERG, DE ;

LAPPERT, MF ;

THOMAS, KM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (21) :893-895

[4]

DAVIDSON PJ, 1973, J CHEM SOC CHEM COMM, P317

[5] REACTIONS OF COMPLEX-BOUND CARBENE ANALOGS .2. SYNTHESIS AND VIBRATIONAL-SPECTRA OF PENTACARBONYL[CHLORO(DI-TERT-BUTYLPHOSPHINO)STANNIO]-METAL(VI-A) COMPLEXES [J].

DUMONT, WW ;

NEUDERT, B .

CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (06) :2267-2272

[6] TRANSITION-METAL CARBINE COMPLEXES .2. TRANS HALODIETHYLAMINOCARBINETETRACARBONYL COMPLEXES OF TUNGSTEN FROM ETHOXYDIETHYL AMINOCARBENEPENTACARBONYLTUNGSTEN(0) [J].

FISCHER, EO ;

KREIS, G ;

KREISSL, FR ;

KALBFUS, W ;

WINKLER, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 65 (02) :C53-C56

[7] TRANSITION-METAL CARBENE COMPLEXES .38. ARYLALKOXY, ARYLDIALKYLAMINO AND DIALKYLA,INOALKOXYCARBENES AS LIGANDS IN COMPLEXES OF TYPE FE(CO)4L [J].

FISCHER, EO ;

LYNCH, J ;

MULLER, J ;

KREITER, CG ;

WINKLER, E ;

BECK, HJ .

CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (01) :162-&

[8] BIS(DIMETHYLAMIDO)TIN(II) - SYNTHESIS AND CHARACTERIZATION [J].

FOLEY, P ;

ZELDIN, M .

INORGANIC CHEMISTRY, 1975, 14 (09) :2264-2267

[9] MONOMERIC, VOLATILE BIVALENT AMIDES OF GROUP-IVB ELEMENTS, M(NR12)2 AND M(NR1R2)2 (MDOUBLE-BONDGE, SN, OR PB - R1DOUBLE-BONDME3SI, R2DOUBLE-BONDME3C) [J].

HARRIS, DH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (21) :895-896

[10]

JUTZI P, 1976, CHEM BER-RECL, V109, P3473, DOI 10.1002/cber.19761091026