STRONG INTERACTIONS IN GAS-PHASE REACTIONS - F + HN3 SYSTEM

被引:35
作者
SLOAN, JJ [1 ]
WATSON, DG [1 ]
WRIGHT, JS [1 ]
机构
[1] CARLETON UNIV,DEPT CHEM,OTTAWA K1S 5B6,ONTARIO,CANADA
关键词
D O I
10.1016/0301-0104(79)80100-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The gas phase reaction between F atoms and hydrazoic acid has been studied by arrested relaxation infrared chemiluminescence. The interpretation of these results has been facilitated by the calculation of several important features of the potential energy surface by the semi-empirical CNDO/2 molecular orbital method. The results suggest that the reaction may proceed via a long-lived HFN3 intermediate species. © 1979.
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页码:1 / 8
页数:8
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