SUPERSTRUCTURES OF TI2S3(4H)

被引：16

作者：

ONODA, M

SAEKI, M

KAWADA, I

机构：

[1] National Institute for Researches in Inorganic Materials, Ibaraki, 300-31, 1-1, Namiki, Sakura-Mura, Niihari-Gun

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1979年 / 457卷 / 10期

关键词：

D O I：

10.1002/zaac.19794570107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Superstructures related to 4H type Ti2S3 (hexagonal unit cell: a, c) are examined by the X‐ray diffraction work for several compositions, and the ordered arrangements of titanium vacancies are studied. The space group of TiS1.46 annealed at 500 or 700°C is Cc and the parameters of the monoclinic unit cell are: A = 5.9439(5) Å = √3 a, B = 10.295(1) Å = 3a, C = 22.858(3) Å = 2c and β = 90.0°. The space group of TiS1.51 annealed at 500, 700 or 900°C is also Cc and the parameters of the rectangular monoclinic unit cell are: A = 10.286(1) Å = 3a, B = 5.9383(6) Å = √3 a, C = 34.924(5) Å = 3c and β = 90.0°. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：62 / 74

页数：13

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