ORGANIC ELECTROSYNTHESIS WITH A SACRIFICIAL ANODE - CHEMICAL REDUCTIVE DEGRADATION OF THE SOLVENT N,N-DIMETHYL FORMAMIDE

被引：21

作者：

SABOUREAU, C ^{[1
]}

TROUPEL, M ^{[1
]}

PERICHON, J ^{[1
]}

机构：

[1] CNRS,ELECTROCHIM CATALYSE & SYNTHESE ORGAN LAB,UM 28,2 AVE HENRI DUNANT,F-94320 THIAIS,FRANCE

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1990年 / 20卷 / 01期

关键词：

D O I：

10.1007/BF01012477

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

When electrolyses using a sacrificial magnesium anode are carried out in DMF as solvent, an overconsumption of the metal is observed (10 to 60%) which principally depends on the temperature and the current density. It has been shown that the electrochemical scouring of magnesium induces a chemical reduction of DMF and a possible pathway is proposed. © 1990 Chapman and Hall Ltd.

引用

页码：97 / 101

页数：5

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