CHIRAL RHODIUM(II) CARBOXAMIDES - A NEW CLASS OF CATALYSTS FOR ENANTIOSELECTIVE CYCLOPROPANATION REACTIONS

被引:130
作者
DOYLE, MP
BRANDES, BD
KAZALA, AP
PIETERS, RJ
JARSTFER, MB
WATKINS, LM
EAGLE, CT
机构
[1] Department of Chemistry, Trinity University, San Antonio
关键词
D O I
10.1016/S0040-4039(00)97128-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chiral Rh2L4 (L = 4-substituted-oxazolidinones and methyl 2-pyrrolidone-5-carboxylate) having two nitrogen-rhodium bonds in the cis geometry at each rhodium face are effective catalysts for enantioselective intermolecular cyclopropanation reactions. © 1990.
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页码:6613 / 6616
页数:4
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