MOLECULAR MECHANISM OF ALKENE EPOXIDATION - A MODEL STUDY WITH 3,3-DIMETHYL-1-BUTENE ON AG(111)

被引:39
作者
MUKOID, C [1 ]
HAWKER, S [1 ]
BADYAL, JPS [1 ]
LAMBERT, RM [1 ]
机构
[1] UNIV CAMBRIDGE,DEPT CHEM,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
关键词
D O I
10.1007/BF00764871
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
On chlorine-promoted Ag(111) oxygen adatoms selectively oxidise 3,3-dimethyl-1-butene (DMB) to the corresponding epoxide with very high selectivity providing direct verification of the mechanism advanced earlier for alkene epoxidation over single crystal silver and silver catalysts. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.
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页码:57 / 61
页数:5
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