ORGANOMETALLIC REACTIONS IN AQUEOUS-MEDIA WITH INDIUM

被引：303

作者：

LI, CJ ^{[1
]}

CHAN, TH ^{[1
]}

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 48期

关键词：

D O I：

10.1016/0040-4039(91)85028-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylation reactions of aldehydes and ketones occurred smoothly with indium metal in aqueous media. Compared to similar reactions with zinc and tin, the reaction with indium proceeds without the need of any promoter. The reaction can be extended to the synthesis of 2-methylene-gamma-lactone 6 via the condensation of carbonyl compounds with 2-bromomethylacrylate 4.

引用

页码：7017 / 7020

页数：4

共 16 条

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