STEREOSELECTIVE REACTIONS OF ALPHA-SILYLALLYL ANIONS WITH CARBONYL-COMPOUNDS

被引：16

作者：

CHAN, TH

LABRECQUE, D

机构：

[1] Department of Chemistry McGill University Montreal

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)74699-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha-silylallyl anions of the type 6 react with carbonyl compounds at the gamma-position, and stereoselectively to give the E- or Z-isomer depending on the reaction conditions. Solvent and reaction temperature play a critical role in the controle of stereoselectivity.

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页码：7997 / 8000

页数：4

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