THE X-RAY CRYSTAL-STRUCTURE OF BIS(DICYCLOHEXYLDITHIOPHOSPHATO)CADMIUM(II)

被引：20

作者：

CASAS, JS

CASTINEIRAS, A

GARCIATASENDE, MS

SANCHEZ, A

SORDO, J

VAZQUEZLOPEZ, EM

机构：

[1] Departamento de Química Inorgánica, Universidade de Santiago de Compostela, 15706 Santiago de Compostela, Galicia

来源：

POLYHEDRON | 1995年 / 14卷 / 15-16期

关键词：

D O I：

10.1016/0277-5387(95)00036-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound bis(dicyclohexyldithiophosphato)cadmium(II), [Cd {S2P (OCy)(2)}(2)], has been obtained by reacting cadmium(II) perchlorate with the sodium salt of dicyclohexyldithiophosphoric acid in ethanol. Its structure was solved by X-ray diffraction. The structure consists of dimers in which each metal centre is coordinated by a chelating ligand and two bridging ligands, giving a coordination number of 4. The two bridging ligands and the two cadmium atoms form an eight-membered ring with a twisted chair conformation.

引用

页码：2055 / 2058

页数：4

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