CHEMICAL-VAPOR TRANSPORT OF INTERMETALLIC SYSTEMS CHEMICAL-TRANSPORT OF CU/AG-MIXED CRYSTALS

被引：16

作者：

GERIGHAUSEN, S ^{[1
]}

BINNEWIES, M ^{[1
]}

机构：

[1] UNIV HANNOVER,INST ANORGAN CHEM,D-30161 HANNOVER,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 06期

关键词：

CHEMICAL TRANSPORT REACTIONS; CU/AG-MIXED CRYSTALS; GAS-PHASE ABOVE CUI/AGI; THERMODYNAMIC CALCULATIONS;

D O I：

10.1002/zaac.19956210605

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By means of chemical transport reaction it is possible to prepare Cu-rich and Ag-rich mixed crystals in the Cu/Ag system. The composition of individual deposited crystals was different. Mass-spectrometric analysis of the gas-phase above CuI/AgI has shown the formation of CuAg2I3,g and Cu(2)AgI3,g. Thermodynamic computations explain the formation of crystals as well as the reaction conditions.

引用

页码：936 / 940

页数：5