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CROSS-POLYMERIZATION OF POLY(ALPHA,OMEGA-ALKYLDIYNE) MACROMONOMERS
被引:11
作者
:
BUTERA, RJ
论文数:
0
引用数:
0
h-index:
0
机构:
CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106
BUTERA, RJ
SIMICGLAVASKI, B
论文数:
0
引用数:
0
h-index:
0
机构:
CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106
SIMICGLAVASKI, B
LANDO, JB
论文数:
0
引用数:
0
h-index:
0
机构:
CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106
LANDO, JB
机构
:
[1]
CASE WESTERN RESERVE UNIV,DEPT MACROMOLEC SCI,CLEVELAND,OH 44106
[2]
CASE WESTERN RESERVE UNIV,DEPT CHEM,CLEVELAND,OH 44106
来源
:
MACROMOLECULES
|
1990年
/ 23卷
/ 01期
关键词
:
D O I
:
10.1021/ma00203a035
中图分类号
:
O63 [高分子化学(高聚物)];
学科分类号
:
070305 ;
080501 ;
081704 ;
摘要
:
The solid-state cross-polymerization reactions of several poly(α,ω-alkyldiyne) macromonomers [formula-omited], (where n = 3, 5, and 8) were characterized. UV-vis and resonance Raman spectra were recorded as a function of conversion, and the results show that a broad distribution of conjugation lengths is present in the partially cross-polymerized macromonomers. Results from samples in which the cross-polymerization was initiated with UV light were compared with those obtained by using samples that were thermally initiated. It was found that the distribution of conjugation lengths is probably caused by constraints imposed upon the growing poly(diacetylene) (PDA) chains by the crystallite size distribution and the crystallite defect density distribution of the sample as well as by UV-induced chain degradation (for those samples that were initiated with UV light). Resonance Raman spectra of the three macromonomer systems investigated show that the low-frequency bands are mixed modes that are primarily due to motions of the aliphatic spacer groups. The intensity behavior of the 720 and 1211 cm-1 bands indicates that a structural change takes place in the aliphatic side chains after about 1 min of UV exposure. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码:199 / 210
页数:12
相关论文
共 26 条
[1]
BATCHELDER DN, 1984, ADV INFRARED RAMAN S, V11, P133
[2]
RAMAN SPECTRAL SHIFTS RELEVANT TO ELECTRON DELOCALIZATION IN POLYDIACETYLENES
BAUGHMAN, RH
论文数:
0
引用数:
0
h-index:
0
机构:
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
BAUGHMAN, RH
WITT, JD
论文数:
0
引用数:
0
h-index:
0
机构:
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
WITT, JD
YEE, KC
论文数:
0
引用数:
0
h-index:
0
机构:
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
YEE, KC
[J].
JOURNAL OF CHEMICAL PHYSICS,
1974,
60
(12)
: 4755
-
4759
[3]
TEMPERATURE-DEPENDENT OPTICAL-ABSORPTION OF PARTIALLY POLYMERIZED DIACETYLENE CRYSTALS
BLOOR, D
论文数:
0
引用数:
0
h-index:
0
BLOOR, D
HUBBLE, CL
论文数:
0
引用数:
0
h-index:
0
HUBBLE, CL
[J].
CHEMICAL PHYSICS LETTERS,
1978,
56
(01)
: 89
-
92
[4]
THERMAL-BEHAVIOR OF POLY(1,8-NONADIYNE) AND ITS CROSS-POLYMERIZED PRODUCT
BUTERA, RJ
论文数:
0
引用数:
0
h-index:
0
BUTERA, RJ
LANDO, JB
论文数:
0
引用数:
0
h-index:
0
LANDO, JB
[J].
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,
1989,
27
(12)
: 2451
-
2468
[5]
BUTERA RJ, 1988, THESIS CASE W RESERV
[6]
COMMENTS ON THE STRUCTURE OF POLYDIACETYLENES IN SOLUTION
CHANCE, RR
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
CHANCE, RR
SHAND, ML
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
SHAND, ML
LEPOSTOLLEC, M
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
LEPOSTOLLEC, M
SCHOTT, M
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
SCHOTT, M
[J].
JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS,
1981,
19
(11)
: 529
-
532
[7]
SOLID-STATE POLYMERIZATION OF A DIACETYLENE CRYSTAL - THERMAL, ULTRAVIOLET, AND GAMMA-RAY POLYMERIZATION OF 2,4-HEXADIYNE-1,6-DIOL BIS-(PARA-TOLUENE SULFONATE)
CHANCE, RR
论文数:
0
引用数:
0
h-index:
0
CHANCE, RR
PATEL, GN
论文数:
0
引用数:
0
h-index:
0
PATEL, GN
[J].
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,
1978,
16
(05)
: 859
-
881
[8]
DALE J, 1963, J CHEM SOC, V73
[9]
EFFECTS OF SUBSTITUENT-INDUCED STRAIN ON THE ELECTRONIC-STRUCTURE OF POLYDIACETYLENES
ECKHARDT, H
论文数:
0
引用数:
0
h-index:
0
ECKHARDT, H
BOUDREAUX, DS
论文数:
0
引用数:
0
h-index:
0
BOUDREAUX, DS
CHANCE, RR
论文数:
0
引用数:
0
h-index:
0
CHANCE, RR
[J].
JOURNAL OF CHEMICAL PHYSICS,
1986,
85
(07)
: 4116
-
4119
[10]
ENKELMANN V, 1984, ADV POLYM SCI, V63, P92
←
1
2
3
→
共 26 条
[1]
BATCHELDER DN, 1984, ADV INFRARED RAMAN S, V11, P133
[2]
RAMAN SPECTRAL SHIFTS RELEVANT TO ELECTRON DELOCALIZATION IN POLYDIACETYLENES
BAUGHMAN, RH
论文数:
0
引用数:
0
h-index:
0
机构:
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
BAUGHMAN, RH
WITT, JD
论文数:
0
引用数:
0
h-index:
0
机构:
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
WITT, JD
YEE, KC
论文数:
0
引用数:
0
h-index:
0
机构:
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
ALLIED CHEM CORP,MORRISTOWN,NJ 07960
YEE, KC
[J].
JOURNAL OF CHEMICAL PHYSICS,
1974,
60
(12)
: 4755
-
4759
[3]
TEMPERATURE-DEPENDENT OPTICAL-ABSORPTION OF PARTIALLY POLYMERIZED DIACETYLENE CRYSTALS
BLOOR, D
论文数:
0
引用数:
0
h-index:
0
BLOOR, D
HUBBLE, CL
论文数:
0
引用数:
0
h-index:
0
HUBBLE, CL
[J].
CHEMICAL PHYSICS LETTERS,
1978,
56
(01)
: 89
-
92
[4]
THERMAL-BEHAVIOR OF POLY(1,8-NONADIYNE) AND ITS CROSS-POLYMERIZED PRODUCT
BUTERA, RJ
论文数:
0
引用数:
0
h-index:
0
BUTERA, RJ
LANDO, JB
论文数:
0
引用数:
0
h-index:
0
LANDO, JB
[J].
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,
1989,
27
(12)
: 2451
-
2468
[5]
BUTERA RJ, 1988, THESIS CASE W RESERV
[6]
COMMENTS ON THE STRUCTURE OF POLYDIACETYLENES IN SOLUTION
CHANCE, RR
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
CHANCE, RR
SHAND, ML
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
SHAND, ML
LEPOSTOLLEC, M
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
LEPOSTOLLEC, M
SCHOTT, M
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV PARIS 5,DRP,F-75231 PARIS,FRANCE
SCHOTT, M
[J].
JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS,
1981,
19
(11)
: 529
-
532
[7]
SOLID-STATE POLYMERIZATION OF A DIACETYLENE CRYSTAL - THERMAL, ULTRAVIOLET, AND GAMMA-RAY POLYMERIZATION OF 2,4-HEXADIYNE-1,6-DIOL BIS-(PARA-TOLUENE SULFONATE)
CHANCE, RR
论文数:
0
引用数:
0
h-index:
0
CHANCE, RR
PATEL, GN
论文数:
0
引用数:
0
h-index:
0
PATEL, GN
[J].
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,
1978,
16
(05)
: 859
-
881
[8]
DALE J, 1963, J CHEM SOC, V73
[9]
EFFECTS OF SUBSTITUENT-INDUCED STRAIN ON THE ELECTRONIC-STRUCTURE OF POLYDIACETYLENES
ECKHARDT, H
论文数:
0
引用数:
0
h-index:
0
ECKHARDT, H
BOUDREAUX, DS
论文数:
0
引用数:
0
h-index:
0
BOUDREAUX, DS
CHANCE, RR
论文数:
0
引用数:
0
h-index:
0
CHANCE, RR
[J].
JOURNAL OF CHEMICAL PHYSICS,
1986,
85
(07)
: 4116
-
4119
[10]
ENKELMANN V, 1984, ADV POLYM SCI, V63, P92
←
1
2
3
→