THE ELECTRICAL DOUBLE-LAYER ON OXIDES - SITE-BINDING IN THE POROUS DOUBLE-LAYER MODEL

被引:25
作者
KLEIJN, JM
机构
[1] Department of Physical and Colloid Chemistry, Wageningen Agricultural University, 6703 HB Wageningen
来源
COLLOIDS AND SURFACES | 1990年 / 51卷
关键词
D O I
10.1016/0166-6622(90)80153-U
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The porous double layer model for the oxide-solution interface introduced by Lyklem a is combined with the ionizable surface group model of Healy and White. The influences of the various parameters of the model on the surface charge and surface potential are evaluated and experimental surface charge density and zeta potential data as a function of pH are simulated. The extended porous double layer model describes adequately all properties typical for the electrical double layer on oxides. © 1990.
引用
收藏
页码:371 / 388
页数:18
相关论文
共 36 条
[1]  
Grahame, Chem. Rev., 41, (1947)
[2]  
Lyklema, J. Electroanal. Chem., 18, (1968)
[3]  
Lyklema, Croat. Chem. Acta, 43, (1971)
[4]  
Kleijn, Lyklema, J. Colloid Interface Sci., 120, (1987)
[5]  
Fokkink, de Keizer, Lyklema, J. Colloid Interface Sci., 127, (1989)
[6]  
Furlong, Yates, Healy, Electrodes of Conductive Metallic Oxides, pp. 367-432, (1981)
[7]  
Berube, de Bruyn, J. Colloid Interface Sci., 28, (1968)
[8]  
Levine, Smith, Discuss Faraday Soc., 52, (1971)
[9]  
Wright, Hunter, Adsorption at solid-liquid interfaces. I. Thermodynamics and the adsorption potential, Australian Journal of Chemistry, 26, (1973)
[10]  
Wright, Hunter, Adsorption at solid-liquid interfaces. II. Models of the electrical double layer at the oxide-solution interface, Australian Journal of Chemistry, 26, (1973)