SYNTHESIS AND IR SPECTRAL STUDIES OF SOME LANTHANIDE NITRATE COMPLEXES WITH 4-BENZOYL-3-METHYL-1-PHENYLPYRAZOL-5-ONE

被引：15

作者：

KUNCHANDY, S ^{[1
]}

INDRASENAN, P ^{[1
]}

机构：

[1] UNIV KERALA,DEPT CHEM,TRIVANDRUM 695034,INDIA

来源：

POLYHEDRON | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1016/S0277-5387(00)81343-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nine complexes of lanthanide nitrates with 4-benzoyl-3-methyl- 1-phenylpyrazol-5-one (BMPP) having the general formula [Ln(BMPP)2(NO3)3] (where Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy and Y) have been synthesized and their IR spectra obtained. In these complexes BMPP acts as a bidentate ligand coordinating through the oxygen of both the carbonyl groups and the nitrate ion acts as a unidentate ligand coordinating through one of the oxygen atoms with the lanthanide ion. © 1990.

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页码：795 / 799

页数：5

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