VINYLCYCLOPROPANE OXYGENATION - ANTIDIASTEREOSELECTIVITY THROUGH AN UNEXPECTED TRANSITION-STATE GEOMETRY

被引：28

作者：

FELDMAN, KS

KRAEBEL, CM

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 17期

关键词：

D O I：

10.1021/jo00043a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ester-substituted vinylcyclopropanes react with molecular oxygen via a radical-mediated [3-atom + 2-atom] addition to form 1,2-dioxolanes with predominantly anti stereochemistry. The degree of anti stereoselectivity can be controlled by the electronic nature of the radical stabilizing substituent R.

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页码：4574 / 4576

页数：3

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