ADAMANTYL CARBONIUM ION AS A DEHYDROGENATING AGENT ITS REACTIONS WITH ESTRONE

被引：27

作者：

LUNN, WHW

FARKAS, E

机构：

[1] Lilly Research Laboratories, Eli Lilly and Company, Indianapolis, IN

来源：

TETRAHEDRON | 1968年 / 24卷 / 23期

关键词：

D O I：

10.1016/S0040-4020(01)96851-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unusual and useful dehydrogenation of estrone of Δ9(11)-estrone has been observed on its reaction with the adamantyl carbonium ion. With modified conditions both t-butyl and adamantyl carbonium ion sources gave 2-substituted estrone derivatives in this reaction. © 1968.

引用

页码：6773 / &

共 7 条

[1]

BEYERMAN HC, 1965, RECL TRAV CHIM PAY-B, V84, P203

[2]

BHACCA NS, 1964, APPLICATIONS NMR SPE, P98

[3] DEHYDROGENATION OF STEROIDAL PHENOLS VIA QUINONE METHIDES [J].