ALKYL AND ARYL SULFENIMIDES

被引：133

作者：

BEHFOROUZ, M

KERWOOD, JE

机构：

[1] Monsanto Company, Organic Chemical Division, Rubber Chemicals Research Laboratories, Nitro, West Virginia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 01期

关键词：

D O I：

10.1021/jo00838a013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl and aryl sulfenimides have been synthesized by the reaction of sulfenyl chlorides with imides in the presence of a tertiary amine. The stability of sulfenyl chloride solutions has been found to be dependent on the temperature and the polarity of the solvent. Decomposition products of cyclohexanesulfenyl chloride have been isolated and identified. Acid and base hydrolyses of cyclohexylthiophthalimide have been studied and the resulting products characterized. Mechanisms and supporting analytical data for the decomposition of cyclohexanesulfenyl chloride and the hydrolyses of cyclohexylthiophthalimide are given. Analytical methods for determination of sulfenyl chlorides and sulfenimides are reported. © 1969, American Chemical Society. All rights reserved.

引用

页码：51 / +

页数：1

共 16 条

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