Anomalous heat capacity of spherical clusters of atoms

被引:24
作者
Burton, J. J. [1 ,2 ]
机构
[1] Univ Illinois, Dept Phys, Urbana, IL 61801 USA
[2] Univ Illinois, Mat Res Lab, Urbana, IL 61801 USA
关键词
D O I
10.1016/0009-2614(69)85118-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The heat capacities of small spherical clusters of atoms arc calculated in the harmonic a for clusters of up to 55 atoms. The heat capacities do not take the expected form C(T) = AT(3) + BT2. The heat capacity per atom is not monotonic in the number of atoms.
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页码:594 / 596
页数:3
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