ISOLATION AND CHARACTERIZATION OF A CATIONIC 19-ELECTRON IRON(III) HYDRIDE COMPLEX, ELECTRON-TRANSFER INDUCED HYDRIDE MIGRATION BY CARBON-MONOXIDE AT AN IRON(III) CENTER

被引：35

作者：

HAMON, P ^{[1
]}

HAMON, JR ^{[1
]}

LAPINTE, C ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM COMPLEXES METAUX TRANSIT & SYNTH ORGAN LAB,CNRS,URA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 21期

关键词：

D O I：

10.1039/c39920001602

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first hypervalent 19-electron metal hydride complex [Fe(C5Me5)(dppe)(CO)H]PF6 3, synthesized from the 17-electron iron(III) hydride complex [Fe(C5Me5)(dppe)H]PF6 2, is isolated and its structure is established by IR, Mossbauer and ESR data; reaction of the iron(III) complex 2 with carbon monoxide causes hydride transfer to the C5Me5 ligand through an electrochemical chemical electrochemical (ECE)-like pathway [dppe = ethylenebis(diphenylphosphine)].

引用

页码：1602 / 1603

页数：2

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