PREPARATION OF CYCLOHEXANE-1,3-DIONE HERBICIDE PRECURSORS BY BIRCH REDUCTION OF 3,5-DIMETHOXYPHENYL-SUBSTITUTED SILANE DERIVATIVES

被引:3
作者
ALI, AS [1 ]
LIEPA, AJ [1 ]
THOMAS, MD [1 ]
WILKIE, JS [1 ]
WINZENBERG, KN [1 ]
机构
[1] CSIRO,DIV CHEM & POLYMERS,PRIVATE BAG 10,ROSEBANK MDC,CLAYTON,VIC 3169,AUSTRALIA
关键词
D O I
10.1071/CH9941205
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Birch reduction of the silane derivatives (3a-d), prepared from Grignard cross-coupling reactions, afforded the cyclohexane-1,3-dione derivatives (5a-d) after acid hydrolysis. Compounds (5a-d) are precursors to silicon-containing herbicides of the general structure (8).
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页码:1205 / 1210
页数:6
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