SYNTHESIS AND POLYMERIZATION OF GEM-METHYL(VINYLBENZYL)TETRACHLOROCYCLOTRIPHOSPHAZENE

被引：9

作者：

BOSSCHER, G ^{[1
]}

VANDEGRAMPEL, JC ^{[1
]}

机构：

[1] UNIV GRONINGEN,DEPT POLYMER CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS | 1995年 / 5卷 / 03期

关键词：

SUBSTITUTED STYRENE; CHLOROCYCLOTRIPHOSPHAZENE; RADICAL HOMO- AND COPOLYMERIZATION;

D O I：

10.1007/BF01057893

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new styrene-substituted chlorocyclotriphosphazene, gem-methyl(vinylbenzyl) tetrachlorocyclotriphosphazene, has been prepared from vinylbenzylmagnesium chloride and hexachlorocyclotriphosphazene. The organosubstituted chlorocyclotriphosphazene has been used in radical homo- and copolymerization with methyl methacrylate. The reactivity ratios for the MMA copolymerization show a small effect of the phosphazene ring on the olefin reactivity. All these polymers exhibit flame-retardant properties.

引用

页码：209 / 216

页数：8

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