1-1 MOLYBDENUM(VI) CITRIC-ACID COMPLEXES

被引：42

作者：

SAMOTUS, A

KANAS, A

DUDEK, M

GRYBOS, R

HODOROWICZ, E

机构：

[1] Faculty of Chemistry, Jagiellonian University, Kraków, 30-060

来源：

TRANSITION METAL CHEMISTRY | 1991年 / 16卷 / 05期

关键词：

D O I：

10.1007/BF01024315

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes obtained by crystallisation from an aqueous solution of molybdate and citric acid (H4cit) at pH 4-8 have Mo:cit ratio 1:1. The new complexes have been characterised by a variety of methods in the solid state and in solution. On this basis two dimeric species, [(MoO2)2O(citH)2]4- and [(MoO2)2O(cit)2]6-, and a monomeric species [MoO3(cit)OH2]4- are proposed.

引用

页码：495 / 499

页数：5

共 19 条

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