OXIDATIVE ADDITION OF PHENYLPHOSPHOLE - X-RAY CRYSTAL-STRUCTURES OF 2 RING-OPENED PRODUCTS [OS3(MU-3-PHPC4H4)(CO)X] WHERE X = 8 OR 9

被引：14

作者：

ARCE, AJ ^{[1
]}

DESANCTIS, Y ^{[1
]}

MANZUR, J ^{[1
]}

DEEMING, AJ ^{[1
]}

POWELL, NI ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 408卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)80111-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phenylphosphole complex [Os3(PhPC4H4)(CO)11] decarbonylates in refluxing octane to yield the oxidative addition product [Os3(mu-3-PhPC4H4)(CO)9] (1) in which ring-opening of both the triosmium and the five-membered phosphole rings has occurred, while further thermal decarbonylation to the cluster [Os3(mu-3-PhPC4H4)(CO)8] (2) leads to metal ring closure and a major reorganisation of the coordination of the 8-electron donating PhPC4H4 ligand.

引用

页码：C18 / C21

页数：4

共 8 条

[1] CARBON HYDROGEN CLEAVAGE VERSUS RING-OPENING IN THE OXIDATIVE ADDITION-REACTIONS OF FURAN, THIOPHENE, SELENOPHENE AND TELLUROPHENE WITH [OS3(CO)10(MECN)2] [J].

ARCE, AJ ;

DEEMING, AJ ;

DESANCTIS, Y ;

MACHADO, R ;

MANZUR, J ;

RIVAS, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1568-1569

[2] COORDINATED PHOSPHOLES FROM THE COUPLING OF ALKYNES WITH BRIDGING PHOSPHIDO LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [CO2(MU-ETA-2 ETA-2'-C4(CO2ME)4PPH2)-(MU-PPH2)(CO)4], [MN2(ETA-4-C4H4PPH2)(MU-PPH2)(CO)6], AND [MN2(MU-ETA-5-C4H4PPH2)(MU-PPH2)-(CO)5] [J].

BRAGA, D ;

CAFFYN, AJM ;

JENNINGS, MC ;

MAYS, MJ ;

MANOJLOVICMUIR, L ;

RAITHBY, PR ;

SABATINO, P ;

WOULFE, KW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (18) :1401-1403

[3] NEW UNSATURATED HETEROCYCLIC SYSTEMS .1. [J].

BRAYE, EH ;

CAPLIER, I ;

HUBEL, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (21) :4406-&

[4] CRYSTAL-STRUCTURES OF THE CLUSTERS [OS3H2(XCH=CHC=C)(CO)9] WHERE X = NME OR S CONTAINING TRIPLY BRIDGING LIGANDS DERIVED FROM N-METHYLPYRROLE AND THIOPHENE [J].

DEEMING, AJ ;

ARCE, AJ ;

DESANCTIS, Y ;

DAY, MW ;

HARDCASTLE, KI .

ORGANOMETALLICS, 1989, 8 (06) :1408-1413

[5]

DEEMING AJ, 1990, ORGANOMETALLICS, V9, P6

[6] OXIDATIVE ADDITION OF FURAN TO A TRIOSMIUM CLUSTER - THE CRYSTAL-STRUCTURE OF [HOS3(CO)10(MU,ETA-2-C4H3O)] [J].

HIMMELREICH, D ;

MULLER, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 297 (03) :341-348

[7]

MATHEY F, 1983, STRUCT BOND, V55, P153

[8]

SHELDRICK GM, 1986, SHELXTL PLUS PACKAGE

← 1 →