ELECTROSYNTHESIS OF LAYERED DOUBLE HYDROXIDES OF NICKEL WITH TRIVALENT CATIONS

被引：104

作者：

INDIRA, L ^{[1
]}

DIXIT, M ^{[1
]}

KAMATA, PV ^{[1
]}

机构：

[1] BANGALORE UNIV,COLL CENT,DEPT CHEM,BANGALORE 560001,KARNATAKA,INDIA

来源：

JOURNAL OF POWER SOURCES | 1994年 / 52卷 / 01期

关键词：

NICKEL HYDROXIDES; LAYERED DOUBLE NICKEL HYDROXIDES; ELECTROSYNTHESIS; ALUMINUM; CHROMIUM; MANGANESE; IRON;

D O I：

10.1016/0378-7753(94)01939-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Layered double hydroxides (LDHs) of nickel with aluminium, chromium, manganese and iron, with the same structure as alpha-nickel hydroxide, have been electrosynthesized. This paves the way for their possible electrochemical impregnation in sintered nickel plaques for use as electrodes in nickel/cadmium batteries. All these LDHs stabilize the alpha-nickel hydroxide structure in alkaline media and retain electrochemical activity, as evidenced by cyclic voltammetric studies. The nickel-aluminium LDH shows the highest coulombic efficiency, while the nickel-iron LDH may prove to be unsuitable as a battery electrode material as it catalyzes oxygen evolution by 50 mV, as compared with pure nickel hydroxide.

引用

页码：93 / 97

页数：5

共 24 条

[1] STUDIES CONCERNING CHARGED NICKEL-HYDROXIDE ELECTRODES .1. MEASUREMENT OF REVERSIBLE POTENTIALS [J].

BARNARD, R ;

RANDELL, CF ;

TYE, FL .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1980, 10 (01) :109-125

[2]

BRACONNIER JJ, 1984, REV CHIM MINER, V21, P496

[3] EFFECT OF COPRECIPITATED METAL-IONS ON THE ELECTROCHEMISTRY OF NICKEL-HYDROXIDE THIN-FILMS - CYCLIC VOLTAMMETRY IN 1M KOH [J].

CORRIGAN, DA ;

BENDERT, RM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (03) :723-728

[4] TEXTURAL AND STRUCTURAL STUDIES ON NICKEL-HYDROXIDE ELECTRODES .2. TURBOSTRATIC NICKEL(II) HYDROXIDE SUBMITTED TO ELECTROCHEMICAL REDOX CYCLING [J].

DELAHAYEVIDAL, A ;

FIGLARZ, M .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1987, 17 (03) :589-599

[5]

DEMAURGESGUERLO.L, 1993, J SOLID STATE CHEM, V104, P359

[6] PREPARATION AND CHARACTERIZATION OF TURBOSTRATIC NI/AL LAYERED DOUBLE HYDROXIDES FOR NICKEL-HYDROXIDE ELECTRODE APPLICATIONS [J].

EHLSISSEN, KT ;

DELAHAYEVIDAL, A ;

GENIN, P ;

FIGLARZ, M ;

WILLMANN, P .

JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (08) :883-888

[7] PREPARATION AND CHARACTERIZATION OF COBALT-SUBSTITUTED ALPHA-NICKEL HYDROXIDES STABLE IN KOH MEDIUM .1. ALPHA'-HYDROXIDE WITH AN ORDERED PACKING [J].

FAURE, C ;

DELMAS, C ;

FOUASSIER, M ;

WILLMANN, P .

JOURNAL OF POWER SOURCES, 1991, 35 (03) :249-261

[8] PREPARATION AND CHARACTERIZATION OF COBALT-SUBSTITUTED ALPHA-NICKEL HYDROXIDE STABLE IN KOH MEDIUM .2. ALPHA-HYDROXIDE WITH A TURBOSTRATIC STRUCTURE [J].

FAURE, C ;

DELMAS, C ;

WILLMANN, P .

JOURNAL OF POWER SOURCES, 1991, 35 (03) :263-277

[9]

FAURE C, 1991, J POWER SOURCES, V35, P291

[10]

GENIN P, 1991, EUR J SOL STATE INOR, V28, P505

← 1 2 3 →