SYNTHESIS OF THE CATIONIC SILYLENEIRON COMPLEX [(ETA-C5H5)FE(CO)(2)=SIME(2-(ME(2)NCH(2))C6H4)]PF6 BY HYDRIDE ABSTRACTION FROM A (HYDROSILYL)IRON COMPLEX WITH PH(3)CPF(6)

被引：23

作者：

KOBAYASHI, H ^{[1
]}

UENO, K ^{[1
]}

OGINO, H ^{[1
]}

机构：

[1] TOHOKU UNIV,GRAD SCH SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1021/om00012a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cationic intramolecular base-stabilized silyleneiron complex, [(eta-C5H5)Fe(CO)(2)=SiMe{2-(Me(2)NCH(2))C6H4}]PF6, was synthesized by hydride abstraction from the (hydrosilyl)iron complex (eta-C5H5)Fe(CO)(2)SiHMe{2-(Me(2)NCH(2))C6H4} with Ph(3)CPF(6). Reaction of the silylene complex with MeOH afforded the methoxysilyl complex [(eta-C5H5)Fe(CO)(2)SiMeOMe{2(Me(2)N(H)CH2)C6H4}]PF6 in good yield. The molecular structures of the silylene and methoxysilyl complexes were determined by X-ray crystal structure analysis.

引用

页码：5490 / 5492

页数：3

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