REGIOSPECIFIC AND STEREOSPECIFIC HYDROXYLATION OF ALICYCLIC HYDROCARBONS WITH SUBSTITUTED PERBENZOIC ACIDS

被引：34

作者：

MULLER, W

SCHNEIDER, HJ

机构：

[1] Fachrichtung Organische Chemie, Universität, Saarbrücken, D-6600

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 05期

关键词：

D O I：

10.1002/anie.197904071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of the type RH → ROH rarely yield homogeneous products. However, substituted perbenzoic acids transform the cyclic “paraffins” cis‐and trans‐1 to 3, X = H, regio‐ and stereospecifically into the corresponding compounds with X = OH. Acyclic alkanes are likewise oxidizable. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：407 / 408

页数：2

共 6 条

[1] DENO NC, 1976, J CHEM SOC CHEM COMM, P1051
[2] Olah G. A., 1978, ANGEW CHEM, V90, P962
[3] OXYFUNCTIONALIZATION OF HYDROCARBONS .9. SUPERACID-CATALYZED OXYGENATION OF ALKANES
OLAH, GA
PARKER, DG
YONEDA, N
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1978, 17 (12) : 909 - 931
[4] SCHNEIDER H, UNPUBLISHED
[5] ENZYMATIC HYDROXYLATIONS WITH MOLECULAR-OXYGEN
ULLRICH, V
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1972, 11 (08) : 701 - &
[6] ULLRICH V, 1972, ANGEW CHEM, V84, P689

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