SYNTHESIS AND MOLECULAR-STRUCTURE OF TRIS(BENZOYL-THIOBENZOYL-METHANATO-O,S)BISMUTH(III)

被引：8

作者：

MISHRA, AK

GUPTA, VD

LINTI, G

NOTH, H

机构：

[1] BANARAS HINDU UNIV, FAC SCI, DEPT CHEM, VARANASI 221005, UTTAR PRADESH, INDIA

[2] UNIV MUNICH, INST INORGAN CHEM, W-8000 MUNICH 2, GERMANY

来源：

POLYHEDRON | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)86932-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title bismuth(III) complexes, Bi[C6H5C(S)CHC(O)C6H4-X]3 (X = H, OMe, Cl in para position) have been synthesized and characterized. The crystal and molecular structure of the complex Bi[C6H5C(S)CHC(O)C6H5]3 has been determined. It crystallizes in the triclinic space group P1BAR. The molecule associates to a loosely held dimer through a weak Bi-S interaction forming a highly asymmetrical four-membered Bi2S2 bridge structure.

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页码：1219 / 1223

页数：5

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