SYNTHESIS AND ELECTROCHEMISTRY OF [(MO(NO)[HB(3,5-ME2-C3HN2)3]CL)2(1,2-(NH)2C6H4)] AND THE CRYSTAL-STRUCTURE OF [(MO(NO)[HB(3,5-ME2C3HN2)3]I)2(1,2-(NH)2C6H4)]

被引：12

作者：

ALOBAIDI, NJ

MCWHINNIE, SLW

HAMOR, TA

JONES, CJ

MCCLEVERTY, JA

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

[2] AL MUSTANSIRIYAH UNIV,COLL SCI,DEPT CHEM,BAGHDAD,IRAQ

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 23期

关键词：

D O I：

10.1039/dt9920003299

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclic voltammetry of the 1,2-phenylenediamide-bridged bimetallic complex [{Mo(NO)L(Cl)}2{1,2-(NH)2C6H4}] [L= HB(3,5-Me2C3HN2)3] has revealed two one-electron reduction processes separated by 770 mV, a value which is in accord with the presence of strongly interacting molybdenum centres but intermediate between those found for the corresponding complexes containing 1,4- and 1,3-disubstituted aryl bridging groups. The crystal structure of [{Mo(NO)L(I)}2{1,2-(NH)2C6H4}] has been determined. It contains Mo-N(arylamide) distances of 1.957(6) angstrom and reveals a non-planar structure for the MoN(amide)-C-C-N(amide)Mo moiety which may account for the lower than expected Mo...Mo interaction detected electrochemically.

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页码：3299 / 3302

页数：4

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