POLYMER-BASED ELECTROCHROMIC DEVICES .1. POLY(3-METHYLTHIOPHENES)

被引：59

作者：

MASTRAGOSTINO, M ^{[1
]}

ARBIZZANI, C ^{[1
]}

BONGINI, A ^{[1
]}

BARBARELLA, G ^{[1
]}

ZAMBIANCHI, M ^{[1
]}

机构：

[1] I CO CEA,I-40066 OZZANO EMILIA,ITALY

来源：

ELECTROCHIMICA ACTA | 1993年 / 38卷 / 01期

关键词：

ELECTROCHROMISM; POLY(3-METHYLTHIOPHENE);

D O I：

10.1016/0013-4686(93)80020-Z

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The basic aspects of electrochromism induced by a p-doping/undoping process of conjugated polymers are briefly described. The most important requisites for an electrochromic device are discussed and polymer electrochromic performance data as well as the test results of a polymer-based variable light transmission electrochromic device are reported. The colour contrast control of conjugated polymers by ''tailoring'' their conjugation length is discussed and spectroelectrochemical data of poly(3-methylthiophenes) electrosynthesized from 3-methylthiophene isomeric dimers and isomeric tetramers are reported.

引用

收藏

页码：135 / 140

页数：6

相关论文

共 13 条

[1] CONFORMATION AND OPTICAL-ABSORPTION PROPERTIES OF THIOPHENE OLIGOMERS - C-13-NMR, UV, AND MMP2 CALCULATIONS OF DI-QUATERTHIOPHENES AND TETRAMETHYL-QUATERTHIOPHENES [J].

BARBARELLA, G ;

BONGINI, A ;

ZAMBIANCHI, M .

ADVANCED MATERIALS, 1991, 3 (10) :494-496

[2] ITO AS COUNTERELECTRODE IN A POLYMER BASED ELECTROCHROMIC DEVICE [J].

CORRADINI, A ;

MARINANGELI, AM ;

MASTRAGOSTINO, M .

ELECTROCHIMICA ACTA, 1990, 35 (11-12) :1757-1760

[3] SYNTHESIS OF OLIGOMERIC 2,5-THIENYLENES - THEIR UV SPECTRA AND OXIDATION POTENTIALS [J].

CUNNINGHAM, DD ;

LAGURENDAVIDSON, L ;

MARK, HB ;

VANPHAM, C ;

ZIMMER, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (13) :1021-1023

[4] POLY(4,4'-DIMETHOXYBITHIOPHENE) - A NEW CONDUCTING POLYMER WITH EXTRAORDINARY REDOX AND OPTICAL-PROPERTIES [J].

DIETRICH, M ;

HEINZE, J .

SYNTHETIC METALS, 1991, 41 (1-2) :503-506

[5] CONDUCTING POLYMERS FROM DIMETHYL-2,2'-BITHIOPHENES [J].

KRISCHE, B ;

HELLBERG, J ;

LILJA, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (19) :1476-1478

[6] STERIC EFFECTS ON THE CONTROLLED POTENTIAL ELECTRO-OXIDATION OF 3-METHYLTHIOPHENE AND THIOPHENE OLIGOMERS AND THE PROPERTIES OF THEIR POLYMER-FILMS [J].

LAGURENDAVIDSON, L ;

PHAM, CV ;

ZIMMER, H ;

MARK, HB ;

ONDRUS, DJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (06) :1406-1414

[7]

LAPKOWSKI M, 1991, J ELECTROANAL CHEM, V310, P57

[8] SYNTHESIS AND CHARACTERIZATION OF 2 REGIOCHEMICALLY DEFINED POLY(DIALKYLBITHIOPHENES) - A COMPARATIVE-STUDY [J].

MAIOR, RMS ;

HINKELMANN, K ;

ECKERT, H ;

WUDL, F .

MACROMOLECULES, 1990, 23 (05) :1268-1279

[9]

MASTRAGOSTINO M, 1989, SYNTHETIC MET, V28, pC501, DOI 10.1016/0379-6779(89)90565-1

[10] OPTICAL-PROPERTIES OF CONDUCTING POLYMERS [J].

PATIL, AO ;

HEEGER, AJ ;

WUDL, F .

CHEMICAL REVIEWS, 1988, 88 (01) :183-200