A Novel Sesquiterpene, 1,2-Epoxyfurano-10(15)-germacren-6-one, from the Resin of Commiphora holtziana Engl.

被引:10
作者
Cavanagh, Iain S. [1 ]
Cole, Michael D. [2 ]
Gibbons, Simon [1 ]
Gray, Alexander I. [1 ]
Provan, Gordon J. [1 ]
Waterman, Peter G. [1 ]
机构
[1] Univ Strathclyde, Dept Pharmaceut Sci, Phytochem Res Labs, Glasgow G1 1XW, Lanark, Scotland
[2] Univ Strathclyde, Dept Pure & Appl Chem, Forens Sci Unit, Glasgow G1 1XW, Lanark, Scotland
关键词
Commiphora holtziana Engl; Burseraceae; Resin exudate; Furanogermacrene; NMR spectroscopy; 1,2-Epoxyfurano-10(15)-germacrend-one;
D O I
10.1002/ffj.2730080108
中图分类号
O69 [应用化学];
学科分类号
081704 [应用化学];
摘要
Three known and one novel furanogermacrenes have been isolated from the resinous exudate of Commiphora holtziana Engl. The structures of the known compounds were determined by comparison of H-1- and C-13-NMR spectra with those already published. The structure of the novel compound was determined as 1.2epoxyfurano10(15)-gemacren-6-one (IV), using spectroscopic techniques. Some previous C-13-NMR assignments for the known compounds were corrected or clarified.
引用
收藏
页码:39 / 41
页数:3
相关论文
共 6 条
[1]
3 NEW FURANOGERMANCREENES FROM MYRRH [J].
BRIESKORN, CH ;
NOBLE, P .
TETRAHEDRON LETTERS, 1980, 21 (16) :1511-1514
[2]
Carroll J.F., 1989, ENTOMOL EXP APPL, V53, P111
[3]
FURANOSESQUITERPENOIDS OF COMMIPHORA-ERYTHRAEA AND C MYRRH [J].
MARADUFU, A .
PHYTOCHEMISTRY, 1982, 21 (03) :677-680
[4]
Provan G. J., 1987, Flavour and Fragrance Journal, V2, P109, DOI 10.1002/ffj.2730020306
[5]
QUADER MA, 1991, TETRAHEDRON, V47, P3611
[6]
Usher G., 1984, DICT PLANTS USED MAN