SYNTHESIS AND CATIONIC PHOTOPOLYMERIZATION OF 1-BUTENYL ETHER MONOMERS

被引：24

作者：

CRIVELLO, JV

YANG, B

机构：

[1] Department of Chemistry, Rensselaer Polytechnic Institute, Troy, New York

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1995年 / 33卷 / 08期

关键词：

1-BUTENYL ETHER MONOMERS; CATIONIC PHOTOPOLYMERIZATION; ISOMERIZATION OF CROTYL ETHERS; DIARYLIODONIUM SALTS; GLYCEROL TRI(1-BUTENYL) ETHER;

D O I：

10.1002/pola.1995.080330821

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new series of cationically polymerizable mono-, di- and multifunctional 1-butenyl ether monomers have been prepared in high yields by the ruthenium catalyzed isomerization of the corresponding crotyl (2-butenyl) ethers. Their straightforward synthesis and high reactivity in photoinitiated cationic polymerization make these monomers highly attractive for a variety of applications. Cationic polymerization rate studies showed that these monomers exhibited comparable reactivity to their related vinyl and 1-propenyl ether analogues. (C) 1995 John Wiley and Sons, Inc.

引用

页码：1381 / 1389

页数：9

共 15 条

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