INTERACTION BETWEEN DEFORMABLE BROWNIAN DROPLETS

被引:35
作者
DENKOV, ND
PETSEV, DN
DANOV, KD
机构
[1] Laboratory of Thermodynamics and Physico-chemical Hydrodynamics, Faculty of Chemistry, Sofia University
关键词
D O I
10.1103/PhysRevLett.71.3226
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The interaction energy between emulsion droplets of micron and submicron size is theoretically studied. The role of the droplet deformability is considered in detail and the equilibrium configuration of a doublet of droplets is determined. It is shown that the attractive interactions may lead to formation of a planar film between two colliding droplets. This deformation is particularly important at high electrolyte concentration and low interfacial tension. The radial distribution function, which can be used for determination of thermodynamic properties of emulsions, is calculated taking into account the droplet deformability.
引用
收藏
页码:3226 / 3229
页数:4
相关论文
共 16 条
[1]  
[Anonymous], 1992, INTERMOLECULAR SURFA
[2]   THE ROLE OF FREE SURFACTANT IN DESTABILIZING OIL-IN-WATER EMULSIONS [J].
ARONSON, MP .
LANGMUIR, 1989, 5 (02) :494-501
[3]   CONTACT ANGLES IN OIL-IN-WATER EMULSIONS STABILIZED BY IONIC SURFACTANTS [J].
ARONSON, MP ;
PRINCEN, HM .
COLLOIDS AND SURFACES, 1982, 4 (02) :173-184
[4]   CONTACT ANGLES ASSOCIATED WITH THIN LIQUID-FILMS IN EMULSIONS [J].
ARONSON, MP ;
PRINCEN, HM .
NATURE, 1980, 286 (5771) :370-372
[5]  
BIBETTE J, 1992, J PHYS II, V2, P401
[6]   DEPLETION INTERACTIONS AND FLUID-SOLID EQUILIBRIUM IN EMULSIONS [J].
BIBETTE, J ;
ROUX, D ;
NALLET, F .
PHYSICAL REVIEW LETTERS, 1990, 65 (19) :2470-2473
[7]   KINETICALLY INDUCED ORDERING IN GELATION OF EMULSIONS [J].
BIBETTE, J ;
MASON, TG ;
GANG, H ;
WEITZ, DA .
PHYSICAL REVIEW LETTERS, 1992, 69 (06) :981-984
[8]  
Churaev N.V., 1987, SURFACE FORCES, V1st edn
[9]  
DANOV KD, IN PRESS J CHEM PHYS
[10]  
DANOV KD, IN PRESS LANGMUIR